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21.
Daniela Ž. Popović Jelena Miladinović Milica D. Todorović Milorad M. Zrilić Joseph A. Rard 《Journal of solution chemistry》2011,40(5):907-920
The osmotic coefficients of K2HPO4(aq) have been measured at T=298.15 K by the isopiestic vapor pressure method over the range of molalities from 1.3846 mol⋅kg−1 to 13.939 mol⋅kg−1 (oversaturation) with CaCl2(aq) as the reference solution. The molalities and osmotic coefficients of saturated solutions in equilibrium with K2HPO4⋅xH2O(cr) were measured simultaneously by the same method. Available literature osmotic coefficients of K2HPO4(aq) at T=298.15 K, and our new experimental data, were combined and modeled using an extended form of Pitzer’s equation and the Clegg-Pitzer-Brimblecombe
equation based on the mole-fraction-composition scale. These equations were used to calculate the activity coefficients of
K2HPO4(aq) at T=298.15 K. 相似文献
22.
<正>Coarse-graining of some sort is a fundamental and unavoidable step in any attempt to derive the classical mechanical behavior from the quantum formalism.We utilize the two-mode Bose-Hubbard model to illustrate how different coarse-grained systems can be naturally associated with a fixed quantum system if it is compatible with different dynamical algebras.Alternative coarse-grained systems generate different evolutions of the same physical quantities,and the difference becomes negligible only in the appropriate macro-limit. 相似文献
23.
Jennifer M. Ruddock Nikola Zotev Brian Stankus Haiwang Yong Darren Bellshaw Sbastien Boutet Thomas J. Lane Mengning Liang Sergio Carbajo Wenpeng Du Adam Kirrander Michael Minitti Peter M. Weber 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(19):6437-6441
Time‐resolved pump–probe gas‐phase X‐ray scattering signals, extrapolated to zero momentum transfer, provide a measure of the number of electrons in a system, an effect that arises from the coherent addition of elastic scattering from the electrons. This allows to identify reactive transients and determine the chemical reaction kinetics without the need for extensive scattering simulations or complicated inversion of scattering data. We examine the photodissociation reaction of trimethylamine and identify two reaction paths upon excitation to the 3p state at 200 nm: a fast dissociation path out of the 3p state to the dimethyl amine radical (16.6±1.2 %) and a slower dissociation via internal conversion to the 3s state (83.4±1.2 %). The time constants for the two reactions are 640±130 fs and 74±6 ps, respectively. Additionally, it is found that the transient dimethyl amine radical has a N?C bond length of 1.45±0.02 Å and a C?N?C bond angle of 118°±4°. 相似文献
24.
Thomas Zimmermann Nikola Pustet Albrecht Mannschreck 《Monatshefte für Chemie / Chemical Monthly》2000,364(3):1083-1090
The enantiomers of substituted spiro[cyclohexadiene-dihydroacridines] were separated by enantioselective liquid chromatography with the sorbent/solvent systems triacetylcellulose/methanol, tris-(3,5-dimethylphenylcarbamoyl)-cellulose/silica gel (Chiralcel ODTM)/n-heptane/2-propanol, and (+)-poly-(trityl methacrylate)/silica gel/n-heptane/2-propanol. Interconversion barriers of the enantiomers were determined for a series of derivatives by thermal racemization. Electrocyclic ring opening/ring closure in terms of the Woodward-Hoffmann rules is discussed for the enantiomerization mechanism; the interconversion of the enantiomers by enolization is ruled out by deuterium exchange experiments. 相似文献
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Nikola Peřinka Markéta Držková Milena Hajná Bohumil Jašúrek Petra Šulcová Tomáš Syrový Marie Kaplanová Jaroslav Stejskal 《Journal of Thermal Analysis and Calorimetry》2014,116(2):589-595
The polyaniline dispersions stabilized with poly(N-vinylpyrrolidone) (PANI/PVP) were synthesized by oxidative polymerization with different mass ratios of PANI and PVP and different molar concentrations of the components in the polymerization mixture. The composite powders prepared from colloidal PANI/PVP dispersions were characterized by thermogravimetry and differential thermal analysis. The change in the ratio of PANI and PVP as well as the starting molar concentrations of aniline hydrochloride and oxidant has influence on the resulting properties of the dispersions. Concerning the doping, the results show that PANI/PVP powders are stable up to approximately 160 °C. Degradation of polymer chains starts at temperatures above 250 °C. The PANI/PVP composite powders with lower content of PANI exhibit slightly higher thermal stability. Further, colloidal PANI/PVP dispersions were screen-printed on aluminum foil for infrared spectroscopic characterization and on poly(ethylene terephthalate) foil for electrical measurements. The sheet resistance of printed layers measured by two-point probe was of the order of tens to thousands of kΩ sq?1. The influence of both the change in the composition and the drying temperature is discussed. 相似文献
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Nikola Kompa 《Acta Analytica》2005,20(1):16-28
The basic idea of conversational contextualism is that knowledge attributions are context sensitive in that a given knowledge
attribution may be true if made in one context but false if made in another, owing to differences in the attributors’ conversational
contexts. Moreover, the context sensitivity involved is traced back to the context sensitivity of the word “know,” which,
in turn, is commonly modelled on the case either of genuine indexicals such as “I” or “here” or of comparative adjectives
such as “tall” or “rich.” But contextualism faces various problems. I argue that in order to solve these problems we need
to look for another account of the context sensitivity involved in knowledge attributions and I sketch an alternative proposal. 相似文献
30.
Marijana??akovi?Email author Maja?Do?en Zora?Popovi?Email author 《Journal of chemical crystallography》2011,41(2):180-185